Creationists claim that argon escape renders age determinations invalid. However, any escaping argon gas would lead to a determined age younger, not older, than actual. The creationist "argon escape" theory does not support their young earth model. The argon age determination of the mineral can be confirmed by measuring the loss of potassium. In old rocks, there will be less potassium present than was required to form the mineral, because some of it has been transmuted to argon. The decrease in the amount of potassium required to form the original mineral has consistently confirmed the age as determined by the amount of argon formed.

See Carbon 14 Dating in this web site. The nuclide rubidium decays, with a half life of Strontium is a stable element; it does not undergo further radioactive decay. Do not confuse with the highly radioactive isotope, strontium Strontium occurs naturally as a mixture of several nuclides, including the stable isotope strontium If three different strontium-containing minerals form at the same time in the same magma, each strontium containing mineral will have the same ratios of the different strontium nuclides, since all strontium nuclides behave the same chemically.

Note that this does not mean that the ratios are the same everywhere on earth. It merely means that the ratios are the same in the particular magma from which the test sample was later taken. As strontium forms, its ratio to strontium will increase. Strontium is a stable element that does not undergo radioactive change. In addition, it is not formed as the result of a radioactive decay process. The amount of strontium in a given mineral sample will not change. Therefore the relative amounts of rubidium and strontium can be determined by expressing their ratios to strontium It turns out to be a straight line with a slope of The corresponding half lives for each plotted point are marked on the line and identified.

It can be readily seen from the plots that when this procedure is followed with different amounts of Rb87 in different minerals , if the plotted half life points are connected, a straight line going through the origin is produced. These lines are called "isochrons". The steeper the slope of the isochron, the more half lives it represents. When the fraction of rubidium is plotted against the fraction of strontium for a number of different minerals from the same magma an isochron is obtained. If the points lie on a straight line, this indicates that the data is consistent and probably accurate.

An example of this can be found in Strahler, Fig If the strontium isotope was not present in the mineral at the time it was formed from the molten magma, then the geometry of the plotted isochron lines requires that they all intersect the origin, as shown in figure However, if strontium 87 was present in the mineral when it was first formed from molten magma, that amount will be shown by an intercept of the isochron lines on the y-axis, as shown in Fig Thus it is possible to correct for strontium initially present. The age of the sample can be obtained by choosing the origin at the y intercept.

Note that the amounts of rubidium 87 and strontium 87 are given as ratios to an inert isotope, strontium However, in calculating the ratio of Rb87 to Sr87, we can use a simple analytical geometry solution to the plotted data.

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- Radiometric Dating!
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Again referring to Fig. Since the half-life of Rb87 is When properly carried out, radioactive dating test procedures have shown consistent and close agreement among the various methods.

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If the same result is obtained sample after sample, using different test procedures based on different decay sequences, and carried out by different laboratories, that is a pretty good indication that the age determinations are accurate. Of course, test procedures, like anything else, can be screwed up. Mistakes can be made at the time a procedure is first being developed.

### Radioactive Dating

Creationists seize upon any isolated reports of improperly run tests and try to categorize them as representing general shortcomings of the test procedure. This like saying if my watch isn't running, then all watches are useless for keeping time. Creationists also attack radioactive dating with the argument that half-lives were different in the past than they are at present.

There is no more reason to believe that than to believe that at some time in the past iron did not rust and wood did not burn.

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Furthermore, astronomical data show that radioactive half-lives in elements in stars billions of light years away is the same as presently measured. On pages and of The Genesis Flood, creationist authors Whitcomb and Morris present an argument to try to convince the reader that ages of mineral specimens determined by radioactivity measurements are much greater than the "true" i. The mathematical procedures employed are totally inconsistent with reality. Henry Morris has a PhD in Hydraulic Engineering, so it would seem that he would know better than to author such nonsense.

Apparently, he did know better, because he qualifies the exposition in a footnote stating:. This discussion is not meant to be an exact exposition of radiogenic age computation; the relation is mathematically more complicated than the direct proportion assumed for the illustration. We can see how do deal with this if we take a particular case. The neutron emits an electron to become a proton. We still don't know 87 Sr 0 , the amount of 87 Sr daughter element initially present.

Thus, 86 Sr is a stable isotope, and the amount of 86 Sr does not change through time. So, applying this simplification,. The reason for this is that Rb has become distributed unequally through the Earth over time. For example the amount of Rb in mantle rocks is generally low, i. Thus we could tell whether the rock was derived from the mantle or crust be determining its initial Sr isotopic ratio as we discussed previously in the section on igneous rocks. Two isotopes of Uranium and one isotope of Th are radioactive and decay to produce various isotopes of Pb.

The decay schemes are as follows. Note that the present ratio of. If these two independent dates are the same, we say they are concordant. We can also construct a Concordia diagram, which shows the values of Pb isotopes that would give concordant dates. The Concordia curve can be calculated by defining the following:.

## Calculating Half-Life - Chemistry LibreTexts

Zircon has a high hardness 7. Zircon can also survive metamorphism. Chemically, zircon usually contains high amounts of U and low amounts of Pb, so that large amounts of radiogenic Pb are produced. Other minerals that also show these properties, but are less commonly used in radiometric dating are Apatite and sphene. Discordant dates will not fall on the Concordia curve. Sometimes, however, numerous discordant dates from the same rock will plot along a line representing a chord on the Concordia diagram.

Such a chord is called a discordia. We can also define what are called Pb-Pb Isochrons by combining the two isochron equations 7 and 8. Since we know that the , and assuming that the Pb and Pb dates are the same, then equation 11 is the equation for a family of lines that have a slope.

## Radiometric dating

The answer is about 6 billion years. This argument tells when the elements were formed that make up the Earth, but does not really give us the age of the Earth. It does, however, give a maximum age of the Earth. Is this the age of the Earth? Lunar rocks also lie on the Geochron, at least suggesting that the moon formed at the same time as meteorites.

Modern Oceanic Pb - i. Pb separated from continents and thus from average crust also plots on the Geochron, and thus suggests that the Earth formed at the same time as the meteorites and moon.

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Thus, our best estimate of the age of the Earth is 4. The initial ratio has particular importance for studying the chemical evolution of the Earth's mantle and crust, as we discussed in the section on igneous rocks. Since K is one of the 10 most abundant elements in the Earth's crust, the decay of 40 K is important in dating rocks. But this scheme is not used because 40 Ca can be present as both radiogenic and non-radiogenic Ca. Since Ar is a noble gas, it can escape from a magma or liquid easily, and it is thus assumed that no 40 Ar is present initially. Note that this is not always true.

If a magma cools quickly on the surface of the Earth, some of the Ar may be trapped. If this happens, then the date obtained will be older than the date at which the magma erupted. For example lavas dated by K-Ar that are historic in age, usually show 1 to 2 my old ages due to trapped Ar. Such trapped Ar is not problematical when the age of the rock is in hundreds of millions of years.

The dating equation used for K-Ar is: Some of the problems associated with K-Ar dating are Excess argon. This is only a problem when dating very young rocks or in dating whole rocks instead of mineral separates. Minerals should not contain any excess Ar because Ar should not enter the crystal structure of a mineral when it crystallizes. Thus, it always better to date minerals that have high K contents, such as sanidine or biotite.

click If these are not present, Plagioclase or hornblende. If none of these are present, then the only alternative is to date whole rocks. Some 40 Ar could be absorbed onto the sample surface.

This can be corrected for. Most minerals will lose Ar on heating above o C - thus metamorphism can cause a loss of Ar or a partial loss of Ar which will reset the atomic clock. If only partial loss of Ar occurs then the age determined will be in between the age of crystallization and the age of metamorphism. If complete loss of Ar occurs during metamorphism, then the date is that of the metamorphic event. The problem is that there is no way of knowing whether or not partial or complete loss of Ar has occurred. Examples of questions on this material that could be asked on an exam. Prior to the best and most accepted age of the Earth was that proposed by Lord Kelvin based on the amount of time necessary for the Earth to cool to its present temperature from a completely liquid state.